International Chemical Safety Cards

DIETHYLENE GLYCOL MONOETHYL ETHER

ICSC: 0039

2-(2-Ethoxyethoxy) ethanol
3, 6-Dioxa-1-octanol
DEGEE
C₆H₁₄O₃ / CH₃CH₂OCH₂CH₂OCH₂CH₂OH
Molecular mass: 134.2
ICSC # 0039
CAS # 111-90-0
RTECS # KK8750000
April 19, 2004 Peer reviewed

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Combustible.	NO open flames.	Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION	Above 96°C explosive vapour/air mixtures may be formed.	Above 96°C use a closed system, ventilation.

EXPOSURE
•INHALATION		Ventilation.	Fresh air, rest.
•SKIN	Dry skin.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
•EYES	Redness.	Safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION		Do not eat, drink, or smoke during work.	Rinse mouth.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water.

Separated from strong oxidants. Ventilation along the floor.

R:
S:

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0039

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DIETHYLENE GLYCOL MONOETHYL ETHER

ICSC: 0039

I

M

P

O

R

T

A

N

T

D

A

T

A

PHYSICAL STATE; APPEARANCE:
HYGROSCOPIC COLOURLESS LIQUID.

PHYSICAL DANGERS:

CHEMICAL DANGERS:
Reacts with strong oxidants. The substance can presumably form explosive peroxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.

ROUTES OF EXPOSURE:

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is mildly irritating to the eyes .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin.

PHYSICAL
PROPERTIES

Boiling point: 196-202°C
Melting point: -76°C
Relative density (water = 1): 0.99
Solubility in water: very good
Vapour pressure, Pa at 25°C: 19

Relative vapour density (air = 1): 4.6
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 96°C o.c.
Auto-ignition temperature: 204°C
Octanol/water partition coefficient as log Pow: -0.15 (estimated)

ENVIRONMENTAL
DATA

N O T E S

Poly-solv DE, Dowanal DE, Dioxitol, Carbitol, Carbitol cellosolve and Transcutol are trade names. In addition see ICSC 0040 Diethylene glycol monomethyl ether. Check for peroxides prior to distillation; eliminate if found.

NFPA Code: H 1; F 1; R 0;

ADDITIONAL INFORMATION

ICSC: 0039	DIETHYLENE GLYCOL MONOETHYL ETHER
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.