International Chemical Safety Cards BENZYL BENZOATE ICSC: 0390 Benzoic acid, phenylmethyl ester Benzyl benzenecarboxylate C14H12O2 Molecular mass: 212.2 ICSC #    0390 CAS #     120-51-4 RTECS # DG4200000 EC #         607-085-00-9 April 07, 1997 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION EXPOSURE  •INHALATION Cough. Sore throat. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.  •SKIN MAY BE ABSORBED! Dry skin. Redness. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower.  •EYES Redness. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: P1 filter respirator for inert particles). Ventilation along the floor. Xn symbol R: 22 S: 2-25 SEE IMPORTANT INFORMATION ON BACK ICSC: 0390 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards BENZYL BENZOATE ICSC: 0390 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID OR WHITE SOLID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air. CHEMICAL DANGERS: On combustion, forms toxic and irritating fumes. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. PHYSICAL PROPERTIES Boiling point: 324°C Melting point: 21°C Relative density (water = 1): 1.1 Solubility in water: none Relative vapour density (air = 1): 7.3 Flash point: 148°C Auto-ignition temperature: 480°C Octanol/water partition coefficient as log Pow: 3.97 ENVIRONMENTAL DATA Avoid release to the environment in circumstances different to normal use. N O T E S Transport Emergency Card: TEC (R)-61G06c NFPA Code: H1; F1; R0; ADDITIONAL INFORMATION ICSC: 0390 BENZYL BENZOATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.