International Chemical Safety Cards PHENYL ACETATE ICSC: 0539 Acetic acid, phenyl ester Acetylphenol C8H8O2 / CH3COOC6H5 Molecular mass: 136.1 ICSC #    0539 CAS #     122-79-2 RTECS # AJ2800000 March 25, 1996 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Powder, AFFF, foam, carbon dioxide. EXPLOSION Above 80°C explosive vapour/air mixtures may be formed. Above 80°C use a closed system, ventilation, and explosion-proof electrical equipment. EXPOSURE  •INHALATION  •SKIN Redness. Protective gloves. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 0539 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards PHENYL ACETATE ICSC: 0539 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes and the skin. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 195°C Relative density (water = 1): 1.07 Solubility in water: none Relative vapour density (air = 1): 4.7 Flash point: 80°C Octanol/water partition coefficient as log Pow: 1.49 ENVIRONMENTAL DATA N O T E S Transport Emergency Card: TEC (R)-565 NFPA Code: H1; F2; R0 ADDITIONAL INFORMATION ICSC: 0539 PHENYL ACETATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.