International Chemical Safety Cards p-CYMENE ICSC: 0617 1-Methyl-4-isopropylbenzene Dolcymene Camphogen C10H14 / CH3C6H4CH(CH3)2 Molecular mass: 134.2 ICSC #    0617 CAS #     99-87-6 RTECS # GZ5950000 UN #        2046 April 11, 1997 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Flammable. NO open flames, NO sparks, and NO smoking. Powder, AFFF, foam, carbon dioxide. EXPLOSION Above 47°C explosive vapour/air mixtures may be formed. Above 47°C use a closed system, ventilation, and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding). In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT GENERATION OF MISTS!  •INHALATION Dizziness. Drowsiness. Vomiting. Ventilation. Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.  •SKIN Dry skin. Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Wear protective gloves when administering first aid.  •EYES Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Diarrhoea. Drowsiness. Headache. Nausea. Vomiting. Unconsciousness. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Rest. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours). Fireproof. R: S: UN Hazard Class: 3 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 0617 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards p-CYMENE ICSC: 0617 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air. CHEMICAL DANGERS: Reacts with oxidants. Attacks rubber. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes and the skin . Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The liquid defats the skin. PHYSICAL PROPERTIES Boiling point: 177°C Melting point: -68°C Relative density (water = 1): 0.85 Solubility in water, g/100 ml at 25°C: 0.002 Vapour pressure, Pa at 20°C: 200 Relative vapour density (air = 1): 4.62 Flash point: 47°C c.c. Auto-ignition temperature: 435°C Explosive limits, vol% in air: 0.7-5.6 Octanol/water partition coefficient as log Pow: 4.1 ENVIRONMENTAL DATA N O T E S Transport Emergency Card: TEC (R)-30G35 NFPA Code: H2; F2; R0; ADDITIONAL INFORMATION ICSC: 0617 p-CYMENE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.