International Chemical Safety Cards

HEXACHLOROBENZENE

ICSC: 0895

Perchlorobenzene
HCB
Pentachlorophenylchloride
Phenyl perchloryl
C₆Cl₆
Molecular mass: 284.8

ICSC #    0895
CAS #     118-74-1
RTECS # DA2975000
UN #        2729
EC #         602-065-00-6
March 24, 1999 Peer reviewed

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Combustible.	NO open flames.	Water spray, foam, powder, carbon dioxide.
EXPLOSION

EXPOSURE		PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!
•INHALATION		Local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
•SKIN	MAY BE ABSORBED!	Protective gloves. Protective clothing.	Rinse and then wash skin with water and soap. Refer for medical attention.
•EYES		Face shield, or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION		Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: P3 filter respirator for toxic particles). Chemical protection suit.

Separated from food and feedstuffs. Well closed.

Do not transport with food and feedstuffs.
Note: E
T symbol
N symbol
R: 45-48/25-50/53
S: 53-45-60-61
UN Hazard Class: 6.1
UN Packing Group: III

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0895

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

HEXACHLOROBENZENE

ICSC: 0895

I

M

P

O

R

T

A

N

T

D

A

T

A

PHYSICAL STATE; APPEARANCE:
COLOURLESS TO WHITE SOLID IN VARIOUS FORMS.

PHYSICAL DANGERS:

CHEMICAL DANGERS:
The substance decomposes on heating producing toxic fumes.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.002 mg/m³ A3 (skin) (ACGIH 1998).
MAK: class 4 (1998)

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.

EFFECTS OF SHORT-TERM EXPOSURE:

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the liver and nervous system , resulting in impaired functions of organs and skin lesions. This substance is possibly carcinogenic to humans. Animal tests show that this substance possibly causes toxic effects upon human reproduction.

PHYSICAL
PROPERTIES

Boiling point: 323-326°C
Melting point: 231°C
Density: 1.21
g/cm3
Solubility in water, g/100 ml at 20°C: 0.0000005

Vapour pressure, Pa at 20°C: 0.001
Relative vapour density (air = 1): 9.8
Flash point: 242°C c.c.
Octanol/water partition coefficient as log Pow: 5.5-6.2

ENVIRONMENTAL
DATA

The substance is very toxic to aquatic organisms. In the food chain important to humans, bioaccumulation takes place, specifically in plants and fish. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use.

N O T E S

Depending on the degree of exposure, periodic medical examination is indicated. Do NOT take working clothes home. Amatin, Anticarie, Bunt-cure, No Bunt 80, Bunt-no-more (Dow chemicals), Co-op-hexa (Bayer chemicals), Sanocide, Snieciotox are trade names.

Transport Emergency Card: TEC (R)-61G12c

ADDITIONAL INFORMATION

ICSC: 0895	HEXACHLOROBENZENE
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.