International Chemical Safety Cards METHYL BENZOATE ICSC: 1187 Methyl-benzenecarboxylate Niobe oil C8H8O2 / C6H5COOCH3 Molecular mass: 136.1 ICSC #    1187 CAS #     93-58-3 RTECS # DH3850000 October 10, 1997 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Foam, powder, >carbon dioxide. EXPLOSION Above 83°C explosive vapour/air mixtures may be formed. Above 83°C use a closed system, ventilation. EXPOSURE  •INHALATION Ventilation. Fresh air, rest.  •SKIN Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours). R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 1187 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards METHYL BENZOATE ICSC: 1187 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS, OILY LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air. CHEMICAL DANGERS: OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. See Notes. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 198-200°C Melting point: -12°C Relative density (water = 1): 1.09 Solubility in water: none Vapour pressure, Pa at 39°C: 133 Relative vapour density (air = 1): 4.7 Flash point: 83°C c.c. Octanol/water partition coefficient as log Pow: 2.12 ENVIRONMENTAL DATA N O T E S Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. NFPA Code: H 0; F 2; R 0; ADDITIONAL INFORMATION ICSC: 1187 METHYL BENZOATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.