International Chemical Safety Cards sec-HEXYL ACETATE ICSC: 1335 1,3-Dimethylbutyl acetate Methylisoamyl acetate Acetic acid, 1,3-dimethylbutyl ester 4-Methyl-2-pentanol, acetate C8H16O2 / CH3COOCH(CH3)CH2CH(CH3)2 Molecular mass: 144.2 ICSC #    1335 CAS #     108-84-9 RTECS # SA7525000 UN #        1233 November 23, 1998 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Flammable. NO open flames, NO sparks, and NO smoking. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION Above 45°C explosive vapour/air mixtures may be formed. Above 45°C use a closed system, ventilation, and explosion-proof electrical equipment. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE  •INHALATION Cough. Sore throat. Ventilation, local exhaust, or breathing protection. Fresh air, rest.  •SKIN Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Rinse mouth. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Personal protection: filter respirator for organic gases and vapours. Fireproof. Separated from strong oxidants. R: S: UN Hazard Class: 3 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 1335 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards sec-HEXYL ACETATE ICSC: 1335 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: Reacts with strong oxidants . OCCUPATIONAL EXPOSURE LIMITS: TLV: 50 ppm as TWA; (ACGIH 2004). MAK: IIb (not established but data is available) (DFG 2004). OSHA PEL: TWA 50 ppm (300 mg/m3) NIOSH REL: TWA 50 ppm (300 mg/m3) NIOSH IDLH: 500 ppm ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour. INHALATION RISK: A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract . Exposure at high levels may result in unconsciousness. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 146°C Melting point: -64°C Relative density (water = 1): 0.86 Solubility in water: none Vapour pressure, kPa at 20°C: 0.4 Relative vapour density (air = 1): 5.0 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01 Flash point: 45°C c.c. Explosive limits, vol% in air: 0.9-5.7 ENVIRONMENTAL DATA N O T E S Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response. Transport Emergency Card: TEC (R)-30GF1-III NFPA Code: H1; F2; R0; ADDITIONAL INFORMATION ICSC: 1335 sec-HEXYL ACETATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.