International Chemical Safety Cards LEAD BIS(DIMETHYLDITHIOCARBAMATE) ICSC: 1545 Lead dimethyldithiocarbamate Bis(dimethylcarbamodithioato-S,S') lead Ledate Methyl ledate C6H12N2PbS4 / ((CH3)2NCS•S)2Pb Molecular mass: 447.6 ICSC #    1545 CAS #     19010-66-3 RTECS # OF8850000 October 27, 2004 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION EXPOSURE  •INHALATION Local exhaust or breathing protection. Fresh air, rest.  •SKIN Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Separated from food and feedstuffs . R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 1545 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards LEAD BIS(DIMETHYLDITHIOCARBAMATE) ICSC: 1545 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE POWDER PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the blood and kidneys , resulting in mild anaemia and kidney impairment. PHYSICAL PROPERTIES Melting point: >310°C Density: 2.43 g/cm3 Solubility in water: none ENVIRONMENTAL DATA N O T E S Health effects of exposure to the substance have not been investigated adequately. Environmental effects from the substance have not been investigated. ADDITIONAL INFORMATION ICSC: 1545 LEAD BIS(DIMETHYLDITHIOCARBAMATE) (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.